学科名 化学科 研究分野 基盤化学
教員名 金子克美
電子メール kaneko@pchem2.s.chiba-u.ac.jp
（1） 研究論文など
１． Evaluation of an effective gas storage amount of latent nanoporous Cu-based metal-organic framework, H. Noguchi, A. Kondo, Y. Hattori, H. Kajiro, H. Kanoh, K. Kaneko, J. Phys. Chem.C. 111, 248-254 (2007).
２． Novel Nanostructures of Porous Carbon Synthesized with Zeolite LTA-Template and Methanol,.L. Song, J. Miyamoto, T. Ohba, H. Kanoh, K. Kaneko, J. Phys. Chem. C., 111, 2459-2464 (2007).
３． Choking Effect of Single Wall Carbon Nanotubes on Solvent Adsorption in Radial Breathing Mode H. Honda, C.M. Yang, H. Kanoh, H. Tanaka, T. Ohba, Y. Hattori, S. Utsumi, and K.Kaneko, , J. Phys. Chem. C. 111 (8), 3220-3222 (2007).
４． Nanowindow-Regulated Specific Capacitance of Supercapacitor Electrodes of Single-Wall Carbon Nanohorns, C.-M. Yang, Y.-J. Kim, M. Endo, H. Kanoh, M. Yudasaka, S. Iijima, and K. Kaneko, J. Am. Chem. Soc., 129, 20-21 (2007).
５． RBM Band Shift-Evidenced Dispersion Mechanism of Single-Wall Carbon Nanotube Bundles with NaDDBS, S. Utsumi, M. Kanamaru, H. Honda, H. Kanoh, H.Tanaka, T. Ohkubo, H. Sakai, M. Abe, K. Kaneko, J. Colloid Interface Sci.,308, 276-284 (2007).
６． Effect of nanoscale curvature of single wall carbon nanotubes on adsorption of polycyclic aromatic hydrocarbons, S. Gotovac, H. Honda, Y. Hattori, K. Takahashi, H. Kanoh, K. Kaneko, Nano Lett. 7 (3), 583—587 (2007).
７． Direct Evidence on C-C Single Bonding in Single-Wall Carbon Nanohorn Aggregates, S. Utsumi, H. Honda, Y. Hattori, H. Kanoh, K. Takahashi, H. Sakai, M. Abe, M. Yudasaka, S. Iijima, K. Kaneko, J. Phys. Chem. C. 111(15), 5572-5575 (2007).
８． Defluorination-enhanced hydrogen adsorptivity of activated carbon fibers, Y. Hattori, N. Noguchi, F. Okino, H. Touhara, Y. Nakahigashi, S. Utsumi, H. Tanaka, H. Kanoh, K. Kaneko, Carbon, 45, 1391-1395 (2007).
９． Surface oxygen-dependent water cluster growth in carbon nanospaces with GCMC simulation-aided in situ SAXS, T. Ohba, K. Kaneko, J. Phys.Chem.C. 111, 6207-6214 (2007).
１０． Adsorption of Water on Three-Dimensional Pillared Layer Metal Organic Frameworks, A. Kondo, T. Daimaru, H. Noguchi, T. Ohba, K. Kaneko, H. Kanoh J. Colloid Interface Sci.314 (2), 422-426 (2007).
１１． Cluster−associated filling of water molecules in slit-shaped graphitic nanopores, T. Ohba and K. Kaneko, Mol. Phys, 111, 6207 (2007).
１２． Magnetic anomaly of organic radical molecules confined in nanospace of single wall carbon nanohorn, T. Matsumura, H. Tanaka, K. Kaneko, M. Yudasaka, S. Iijima, and H. Kanoh, J. Phys. Chem. C, 111, 10213-10216 (2007).
１３． Conductive and mesoporous single wall carbon nanohorn/organic aerogel composite, Y. Tao, D. Noguchi, C.-M.Yang, H. Kanoh, H. Tanaka, M. Yudasaka, S. Iijima, K. Kaneko, Langmuir, 23, 9155-9157 (2007).
１４． Investigation of hydrogen storage capacity of various carbon materials, W.X.Xu, K. Takahashi, Y. Matsuo, Y. Hattori, M. Kumagai, S. Ishiyama, K. Kaneko, S. Iijima, International J. Hydrogen Energy, 32, 2504-2512 (2007).
１５． Double-step Gas Sorption of a Two Dimensional Metal-Organic Framework, A.Kondo, H. Noguchi, L. Carlucci, D. M. Proserpio, G. Ciani, H. Kajiro, T. Ohba, H.Kanoh, K. Kaneko, J. Amer. Chem. Soc. 129,12362−12363 (2007).
１６． Nanoscale curvature effect on ordering of N2 molecules adsorbed on single wall carbon nanotube,T.Ohba, T. Matsumura, K. Hata, M. Yumura, S. Iijima, H. Kanoh, K. Kaneko, J. Phys. Chem. C, 111, 15660-15664 (2007).
１７． Pore Characterization of assembly‐structure controlled Single Wall Carbon Nanotube, M. Arai, M. Kanamaru, T. Matsumura, Y. Hattori, S. Utsumi, T. Ohba,H. Tanaka, C. M. Yang, H. Kanoh, F. Okino, H. Touhara, K. Kaneko, Adsorption, in press.
１８． Supercritical Hydrogen Adsorption of Ultramicropore-Enriched Single-Wall Carbon Nanotube Sheet、D. Y. Kim, C-.M. Yang, M. Yamamoto, D. H. Lee, Y. Hattori, K. Takahashi, H. Kanoh, K. Kaneko, J. Phys. Chem. C.111、17448-17451(2007).
１９． Coordinated NH3−Removal Induced Hydrogen Adsorption of Cu−Complex Crystals, A. Kondo, H. Noguchi, H. Kajiro, T. Ohba, K. Kaneko, and H. Kanoh, Langmuir, 24, 170−174 (2008).
２０． Development of Porosity in Carbons from Yeast Grains by Activation with Alkali Metal Carbonates,Y. Urabe, T. Ishikura , K. Kaneko, J. Colloid Interface Sci. 319 381–383 (2008)
２１． Catalytic activities of Pd-tailored single wall carbon Nanohorns, T. Itoh, H. Danjo, W. Sasaki, K. Urita, E. Bekyarova, M. Arai, T. Imamoto, M. Yudasaka, S. Iijima, H, Kanoh, K, Kaneko, Carbon, 46, 172-175 (2008).
２２． Flexible transparent conducting single wall carbon nanotube film with network bridging method, Y II Song, C.M.Yang, D. Y. Kim, H. Kanoh, and K. Kaneko, J. Colloid Interface Sci. 318, 365-371 (2008).
２３． Quantum Sieving Effects for H2 and D2 in Three-Dimensional
Metal-Organic Framework D. Noguchi, H. Tanaka, A Kondo, H.Kajiro, H.Noguchi,T.Ohba, H Kanoh, K. Kaneko, J. Amer.Chem.Soc. 130, 6367-6372(2008).
２４． Fine Nanostructure Analysis of Single-Wall Carbon Nanohorns by Surface Enhanced Raman Scattering, T. Fujimori, K. Urita, Y. Aoki, H. Kanoh, T. Ohba, M. Yudasaka, S. Iijima, K. Kaneko, J. Phys. Chem. C. (Letter) in press.
２５． Mechanochemically Induced sp3-bond-associated Reconstruction of Single Wall Carbon Nanohorns, K. Urita, S. Seki, H. Tuchiya, H. Honda, S. Utsumi, C, Hayakawa, H. Kanoh, T.Ohba, H. Tanaka, M. Yudasaka, S. Iijima, K.Kaneko, J. Phys. Chem. C (Letter) in press
（２）総説,解説、著書、編集など
1. 表面物性工学ハンドブック、丸善、（２００７） 第２２章、カーボンナノチューブによる水素吸蔵、担当 （内海重宣、金子克美）
ナノカーボン、服部義之、金子克美、777-780.
2．ナノカーボンハンドブック 編集委員 エンティエス出版 929ページ (2007) 金子克美、加納博文、カーボンナノホーンの気体吸蔵性、２７６−２８２
3．ナノカーボン材料の構造と水素吸着性 金子克美、有機貯蔵材料とナノ材料―水素社会に向けて―、シーエムシー出版、市川勝監修、第2章 炭素系水素貯蔵材料、82−99 （2007）
4． ナノ構造と気体吸着性、内海重宜，野口大介，金子克美,高分子、５６、７８−８１（２００７）
5. 吸着誘起ナノ構造変化を示す配位高分子錯体、近藤篤、金子克美、ゼオライト、24(3) 73-79 (2007).
6. 電導性に優れる多孔性ナノカーボン含有ポリマー,陶有勝、金子克美,
ケミカルエンジニヤリング, ５２（６）、６４−６８ (2007).
7. Adsorptive properties of novel nanoporous materials, H. Noguchi, A. Kondo, D. Noguchi, D. Y. Kim, T. Ohba, C.M. Yang, H. Kanoh, K. Kaneko, J. Chem.Eng. Japan, 40,(13), 1159-1165 (2007).
8. Storage Function of Carbon Nanospaces for Molecules and Ions, K. Kaneko et. al, One-Dimensional Electronic and Photonic Devices, ecstransactions, 11(8),63-75(2007).
9. ナノカーボンとそのエネルギー貯蔵機能,Cheol-Min Yang, 金子克美
セラミックス、43（２） 105−110(2008)
10. 水素貯蔵材料としてのナノカーボンの特徴と動向、金子克美, 工業材料、
56 (3), 35-39 (2008).
(３)特別研究などの指導実績：
卒業研究（学士）2名 大学院修士修了者3名 博士学位取得人数 5
(４)国際学会およぶ国内学会などの活動関係
4．１ 海外での国際会議における基調講演・招待講演
STRUCTURE OF CONFINED FLUIDS AND IONS,
Workshop on Basic Research need for electrical energy storage, April 2-5, 2007, Bethesda North Marriot, Washington DC, USA Invited
MOLECULES AND IONS CONFINED IN SOLID NANOSPACES
Fourth San Luis Summer School and Symposium on Surfaces, Interfaces and
Catalysis", April 16-22, 2007, Cuvernavaca, Mexico Invited
STRUCTURAL ADSORPTION STUDY ON WATER MOLECULES AND IONS IN CARBON NANOPORES, Carbon2007, Seattle, July 15-20, 2007 Award lecture
STORAGE FUNCTION OF CARBON NANOSPACES FOR MOLECULES AND IONS , Symposium on Nanoscale One-Dimensional Electronic and Photonic Devices at the 212th Meeting of The Electrochemical Society, Washington, DC,October 7-12, 2007 Invited
QUANTUM SIEVING EFFECT OF THREE-DIMENSIONAL CU-BASED ORGANIC FRAMEWORK FOR H2 AND D2, Special symposium :Keith Gubbins 70th Birthday Celebration I at AIChE meeting, Salt Lake City, USA, November 6-7,2007. Invited
STRUCTURE FORMATION MECHANISM OF WATER CONFINED CARBON NANOPORE SPACES , ESF-FWF Conference in Partnership with LFUI,
Water Interfaces in Physics, Chemistry and Biology: A Multi-Disciplinary Approach Universitätszentrum Obergurgl, Austria 8-13 December 2007
Invited
4.2 国内での国際会議あるいは国内学会での招待講演、特別講演など
○ ADSORPTIVE PROPERTIES OF NOVEL NANOPOROUS MATERIALS
International Symposium on Innovative Materials for Processes in Energy Systems. IMPRES Kyoto Oct.28-31 2007 Plenary
○ 電導性に優れる多孔性ナノカーボン含有ポリマー
科学技術振興機構 ＪＳＴホール（市ヶ谷） 平成１９年３月１６日
○ ナノカーボン系での吸着現象
細孔における吸着特性：界面研シンポジウム（東京理科大学総合研究機構）
東京理科大・野田キャンパス・平成１９年 3月10日
○ ナノスペース中の水の不思議 第40回ウォーター研究会セミナー
平成１９年６月23日 国立感染症研究所 早稲田 東京
○ ナノ細孔体の構造と分子吸着機
触媒学会関東地区 千葉地区触媒講演会
2007年6月29日（金）千葉大学自然科学系総合研究棟１
○ 全表面物質の疎水的ナノ空間中の分子系構造異常
日本化学会秋季年会 首都東京大学 平成１９年９月 招待講演
4.3 国際シンポジウムの開催
○Workshop on Frontier Science and Technology of Nanoporous Systems III
(FSTNS III) Januaray 27 (2007) 約80名参加
海外からの招待講演者：
Prof. Keith E. Gubbins (North Carolina State University, USA)
Dr. Peter Branton (British American Tobacco, UK)
Prof. Elena Bekyarova (University of California - Riverside, USA)
Dr. Matthias Thommes (Quantachrome Corp., USA)
Prof. Lucia Carlucci (University of Milano, Italy)
Prof. Nigel Seaton (University of Edinburgh, UK)
○2007 MRS Fall Meeting in Boston
Symposium organizer of Nanophase and Nanocomposite Materials – V
With professor S. Komarneni
November 26 - 30, 2007
(5)教育行政上の役割
自然科学研究科長として、新４研究科体制後の自然科学研究科学生に関する教育上の役割を持ちました。
千葉大学運営協議会委員を務めました。
(6) 学会、国、などへの協力など
Carbon(イギリス), Porous Materials（USA）, Adsorption（USA）, J. Experimental Nanoscience(イギリス) の編集委員
IUPAC committee member in Carbon
日本化学会 コロイド・界面部会の役員
表面 の編集幹事
東京大学物性研究所物性研究所協議会委員
科学研究費委員会専門委員
科学技術・学術審議会専門委員
花王科学芸術財団選考委員
学術創成研究外部評価委員(東京工業大学岩本正和教授、ナノ空間の化学)
新世代研究所「ナノカーボン研究会」委員
(6）国際的な学会賞の受賞
アメリカカーボン学会が３年に１名カーボンサイエンスに寄与のあった研究者に与える学会賞、Charles E. Pettinos Awardを受賞しました。以下が学会の報告です。
The Charles E. Pettinos Award
Professor Katsumi Kaneko
Department of Chemistry, Graduate School of Science
Chiba University, Japan
Professor Katsumi Kaneko of Chiba University, Chiba, Japan, is the recipient of the Charles E. Pettinos Award to be given at Carbon 2007 International Conference on Carbon, which will be held in Seattle, Washington, on July 15-20, 2007. The Charles E. Pettinos Award, sponsored by the Charles E. Pettinos Foundation and the American Carbon Society, is an international award given triennially to a person in recognition of recent outstanding research accomplishments in the field of carbon science and technology.
Professor Kaneko has contributed much to the understanding of porous carbons and the confinement effects they induce. His recent investigations of the confinement effects of carbon nanopores on absorbed gases are ground-breaking. Professor Kaneko has published close to 350 scientific papers and his wide range of research topics include a new adsorbent of iron oxide dispersed activated carbon fiber for supercritical NO; new characterization methods for porous carbons, adsorption properties of porous carbons, and preparation of new types of porous carbons; water adsorption mechanism of hydrophobic porous carbons and dehydration of ions confined in carbon nanopores; pore structures and adsorption properties of nanocarbons; structure determination of molecules adsorbed in carbon nanopores; and supercritical gas adsorption in slit-shaped carbon nanopores. Professor Kaneko is a most knowledgeable expert world-wide on the characterization of the nanopore structures of carbon materials because of his development of advanced pore structure analysis techniques, and he is especially known for his pioneering work on helium adsorption in carbon nanopores. His use
of helium for probing the tiniest pores greatly increased the ability to gain detailed information about the low end of the pore diameter distribution. Professor Kaneko’s studies on the behavior of NO and supercritical gases such as H2 and CH4 in narrow micropores of activated carbons and activated carbon fibers have led to increased interest and new discoveries in the adsorption properties of gases in confined nanospaces of carbon nanotubes and nanohorns. His methodology for determining the adsorption properties of superhigh-surface-area carbons has won many supporters. His studies of water adsorption in confined nanospaces of hydrophobic carbons have led to a much better understanding of the formation of clusters and solid-like behavior of adsorbates. In all these studies, Professor Kaneko has combined the virtues of state-of-the-art experimentation (e.g. He adsorption at 4.2 K and in-situ x-ray diffraction) with state-of-the-art theoretical analyses.
Dr. Kaneko received his B.T. in Applied Chemistry from Yokohama National University, his M.S. in Chemistry from The University of Tokyo and his Dr. Sci. from The University of Tokyo. His thesis was on the Electrical Properties and Defect Structures of Iron Hydroxide Oxides. Dr. Kaneko began his research career as Assistant Professor in the Department of Chemistry and Faculty of Science at Chiba University in 1971, and is currently Professor at Chiba University. Dr. Kaneko was President of the International Adsorption Society until May 2007 and was Editor of Adsorption Science and Technology (UK) from 2003 to 2006.
Professor Kaneko will present his Pettinos Award Lecture titled “Structural Adsorption Studies on Water Molecules and Ions in Carbon Nanopores” at the Carbon 2007 conference.